| Titre : |
Bonding energetics in organometallic compounds |
| Type de document : |
texte imprimé |
| Auteurs : |
T.M Marks, Éditeur scientifique |
| Editeur : |
Washington : American Chemical Society |
| Année de publication : |
1990 |
| Collection : |
ACS Symposium Series num. 428 |
| Importance : |
305 p. |
| Présentation : |
Relié. Graph. |
| Format : |
24 cm |
| ISBN/ISSN/EAN : |
978-0-8412-1791-1 |
| Langues : |
Anglais (eng) |
| Catégories : |
AC.00 Metaux de transition et organometalliques
|
| Mots-clés : |
organometallics compounds transition metals and alloys chemical energeticsbonding theoretical chemistry |
| Index. décimale : |
AC.00 |
| Résumé : |
1- importance of metal-ligand bond energies in organometallic chemistry 2- periodic trends in transition metal bonds to hydrogen, carbon, and nitrogen 3- organometallic reaction energetics from product kinetic energy release distributions 4- methods for determining metal ligand and metal-metal bond energies using fourier transform mass spectrometry 5- gas phase thermochemistry of organometallic and coordination complex ions 6- ionization energy-bond energy relationships in organometallic chemistry 7- thermodynamics and kinetics of transition metal-alkyl homolytic bond dissociation processes 8- cage pair intermediate and activation parameters 9- thermodynamic and kinetic studies of binding nitrogen and hydrogen to complexes of chromium, molybdenum, and tungsten 10- thermodynamic studies of the hydrogenation and reductive coupling of carbon monoxide by rhodium porphyrins 11- metal and ancillary coordination effects on organolanthanideligand bond enthalpies: implications for bonding and reaction patterns 12- novel extensions of the electrostatic covalent approach and calorimetric measurements to organometallic systems 13- metal-ligand bond dissociation energies in cpmn(co)-2l and cr(co)-5(olefin) complexes 14- metal carbon and metal hydrogen bond dissocation enthalpies from classical and nonclassical calorimetric studies 15- adsorbate induced restructruring of surfaces: surface thermodynamic puzzle 16- acid sites on chemically modified molybdenum surfaces 17- absolute electronegativity, hardness and bond energies 18- gas phase chemistry of first row transition metal ions with nitrogen containing compounds 19- periodic trends in the bond energies of transition metal complexes: density functional theory |
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